Journal article
Synthesis of (-)-(Z)-deoxypukalide.
- Abstract:
- (Chemical Equation Presented) Closing the deal: A ring-closing metathesis (RCM)/aromatization protocol, followed by a regioselective Negishi cross-coupling reaction and macrolactonization, with subsequent RCM mediate the synthesis of (-)-(Z)-deoxypukalide in 12 linear steps and 15% overall yield (see retrosynthesis; TBS=tert-butyldimethylsilyl, TIPS=triisopropylsilyl). © 2008 Wiley-VCH Verlag GmbH and Co. KGaA.
- Publication status:
- Published
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Authors
- Journal:
- Angewandte Chemie (International ed. in English) More from this journal
- Volume:
- 47
- Issue:
- 38
- Pages:
- 7314-7316
- Publication date:
- 2008-01-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:34346
- UUID:
-
uuid:8001c0eb-9ea8-4108-a42a-0fa410eaf70c
- Local pid:
-
pubs:34346
- Source identifiers:
-
34346
- Deposit date:
-
2012-12-19
Terms of use
- Copyright date:
- 2008
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