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Structure-activity correlations for Brønsted acid, Lewis acid, and photocatalyzed reactions of exfoliated crystalline niobium oxides

Abstract:

Exfoliated crystalline niobium oxides that contain exposed but interconnected NbO 6 octahedra with different degrees of structural distortion and defects are known to catalyze Brønsted acid (BA), Lewis acid (LA), and photocatalytic (PC) reactions efficiently but their structure–activity relationships are far from clear. Here, three exfoliated niobium oxides, namely, HSr 2 Nb 3 O 10 , HCa 2 Nb 3 O 10 , and HNb 3 O 8 , are synthesized, characterized extensively, and tested for selected BA, LA,...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/cctc.201601131

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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Publisher:
Wiley Publisher's website
Journal:
ChemCatChem Journal website
Volume:
9
Issue:
1
Pages:
144-154
Publication date:
2016-12-23
DOI:
EISSN:
1867-3899
ISSN:
1867-3880
Pubs id:
pubs:668895
URN:
uri:7f670e06-2a23-4d1a-a07a-2e92fe280092
UUID:
uuid:7f670e06-2a23-4d1a-a07a-2e92fe280092
Local pid:
pubs:668895

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