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A metathesis approach to aromatic heterocycles

Abstract:

The ring closing metathesis (RCM) reaction can be used to prepare substituted furans and pyrroles. By utilising a Pd-catalysed coupling reaction with methoxyallene, allylic alcohols and sulfonamides can be converted into substrates that are ideal precursors to ring closing metathesis. After the RCM reaction is complete, the addition of acid promotes an elimination of methanol to form the fully aromatised system. A range of different substitution patterns and functional groups are compatible w...

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Publication status:
Published

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Publisher copy:
10.1002/ejoc.200500113

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Bingham, M More by this author
Journal:
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume:
2005
Issue:
10
Pages:
1969-1971
Publication date:
2005-05-13
DOI:
EISSN:
1099-0690
ISSN:
1434-193X
URN:
uuid:7e3edcad-e47c-4b88-8ccd-62be786214a4
Source identifiers:
39500
Local pid:
pubs:39500

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