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Isotopic polymorphism in pyridine.

Abstract:
Not so simple: It is normally assumed that deuteration has only a minor effect on the stabilities of crystal structures. This assumption is wrong for pyridine. A low-temperature polymorph exists for [D5]pyridine, but not for [H5]pyridine, which adds a further twist to the already unusual structural chemistry of one of the simplest and most familiar laboratory chemicals. (Figure Presented). © 2009 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200803589

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Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
48
Issue:
4
Pages:
755-757
Publication date:
2009-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:104541
UUID:
uuid:7dda6426-3b78-4f38-87b8-f63ed5c97cf4
Local pid:
pubs:104541
Source identifiers:
104541
Deposit date:
2013-11-16

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