Journal article

A cycloaddition-rearrangement approach to the squalestatins

Abstract:: Reaction of diazodiketoester 4 with methyl glyoxylate in toluene in the presence of catalytic rhodium(II) acetate generates the 6,8- dioxabicyclo[3.2.1]octane 5 as a single regio- and stereo-isomer in good yield. Elaboration provides a suitable alcohol 7 for acid-catalysed rearrangement to give the 2,8-dioxabicyclo-[3.2.1]octane skeleton 8 of the squalestatins.

Publication status:: Published

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APA Style

Hodgson, D., Bailey, J., & Harrison, T. (1996). A cycloaddition-rearrangement approach to the squalestatins. TETRAHEDRON LETTERS, 37(26), 4623–4626.

MLA Style

Hodgson, D., et al. “A Cycloaddition-Rearrangement Approach to the Squalestatins.” TETRAHEDRON LETTERS, vol. 37, no. 26, 1996, pp. 4623–26.

Chicago Style

Hodgson, D, J Bailey, and T Harrison. 1996. “A Cycloaddition-Rearrangement Approach to the Squalestatins.” TETRAHEDRON LETTERS 37 (26): 4623–26.
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Publisher copy:: 10.1016/0040-4039(96)00893-3

Authors

+ Hodgson, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Bailey, J More by this author

Role:: Author

+ Harrison, T More by this author

Role:: Author

Journal:: TETRAHEDRON LETTERS More from this journal
Volume:: 37
Issue:: 26
Pages:: 4623-4626
Publication date:: 1996-06-24
DOI:: 10.1016/0040-4039(96)00893-3
ISSN:: 0040-4039

Pubs id:: pubs:45244
UUID:: uuid:7dbc3da3-90d4-4ef4-b1ca-af53e3e9faba
Local pid:: pubs:45244
Source identifiers:: 45244
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1996

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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