Journal article icon

Journal article

Oxidative addition, transmetalation, and reductive elimination at a 2,2'-bipyridyl-ligated gold center

Abstract:

Three-coordinate bipyridyl complexes of gold, [(κ2-bipy)Au-(η2-C2H4)][NTf2], are readily accessed by direct reaction of 2,2′-bipyridine (bipy), or its derivatives, with the homoleptic gold ethylene complex [Au(C2H4)3][NTf2]. The cheap and readily available bipyridyl ligands facilitate oxidative addition of aryl iodides to the Au(I) center to give [(κ2-bipy)Au(Ar)I][NTf2], which undergo first aryl-zinc transmetalation and second C−C reductive elimination to produce biaryl products. The product...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

Actions


Access Document


Files:
Publisher copy:
10.1021/jacs.8b01411

Authors


Harper, MJ More by this author
Arthur, CJ More by this author
Emmett, EJ More by this author
Falconer, RL More by this author
Expand authors...
More from this funder
Grant:
University Research Fellowship
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
140
Issue:
12
Pages:
4440–4445
Publication date:
2018-03-19
Acceptance date:
2018-03-08
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Pubs id:
pubs:831384
URN:
uri:7d1b4869-c4ea-40bb-998c-1bd3a6344930
UUID:
uuid:7d1b4869-c4ea-40bb-998c-1bd3a6344930
Local pid:
pubs:831384
Language:
English
Keywords:

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP