Journal article
Chemoselective carbene insertion into the N−H bonds of NH3·H2O
- Abstract:
- O and enables the generation of electrophilic silver carbene. Water promotes subsequent [1,2]-proton shift to generate N-H insertion products with high chemoselectivity. The result of the reaction is the coupling of an inorganic nitrogen source with either diazo compounds or N-triftosylhydrazones to produce useful primary amines. Further investigations elucidate the reaction mechanism and the origin of chemoselectivity.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Version of record, pdf, 2.3MB, Terms of use)
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- Publisher copy:
- 10.1038/s41467-022-35394-z
Authors
+ National Natural Science Foundation of China
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- Funder identifier:
- 10.13039/501100001809
- Grant:
- 21871043
+ Department of Science and Technology of Jilin Province
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- Funder identifier:
- 10.13039/501100011789
- Grant:
- 20200801065GH
+ National Science Foundation of China | International Cooperation and Exchange Programme
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- Funder identifier:
- 10.13039/501100010896
- Grant:
- 1961130376
- Publisher:
- Nature Research
- Journal:
- Nature Communications More from this journal
- Volume:
- 13
- Issue:
- 1
- Pages:
- 7649-7649
- Article number:
- 7649
- Publication date:
- 2022-12-10
- DOI:
- EISSN:
-
2041-1723
- ISSN:
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2041-1723
- Language:
-
English
- Keywords:
- Pubs id:
-
1314648
- Local pid:
-
pubs:1314648
- Source identifiers:
-
W4311931393
- Deposit date:
-
2026-04-30
- ARK identifier:
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Terms of use
- Copyright date:
- 2022
- Licence:
- CC Attribution (CC BY)
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