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On the difference in valence electron plasmon energy and density of states between beta- and cubic-Si3N4

Abstract:

Core and valence level photoemissionspectra of β- and cubic-Si3N4 have been measured under monochromatic AlKα excitation. Strong satellites to high binding energy of the core lines are shown to arise from excitation of valence electron plasmons during the photoemission process. An increase in the plasmonenergy from 23.45 eV for β-Si3N4 to 26.10 eV for cubic-Si3N4 is of the magnitude expected from the 26% increase in the valence electron density associated with the shock-induced β-to-cubic phase transition. The measuredvalence banddensity of states for cubic-Si3N4 is in agreement with theoretical calculations.

Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.1619568

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Publisher:
American Institute of Physics
Journal:
JOURNAL OF APPLIED PHYSICS More from this journal
Volume:
94
Issue:
10
Pages:
6611-6615
Publication date:
2003-11-15
DOI:
ISSN:
0021-8979


Language:
English
Keywords:
UUID:
uuid:7af4a0f5-c7f3-4476-8ec6-6fdcd28bd570
Local pid:
pubs:38818
Source identifiers:
38818
Deposit date:
2012-12-19

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