Journal article

New chemical insights using weakly supported voltammetry: Ion pairing in the EC 2 reduction of 2,6-diphenylpyrylium in acetonitrile

Abstract:: Pairing effect: Varying the concentration of support electrolyte in the electrochemical EC 2 reduction of 2,6-diphenylpyrylium reveals the presence of ion pairing between the electroactive species and BF 4-. Experiment and theory are shown to be in good agreement only if ion pairing is included in the simulations. This previously unanticipated effect is only observable if voltammetry is performed under conditions of weak support. Copyright © 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

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APA Style

Barnes, E., Wang, Y., Belding, S. R., & Compton, R. (2012). New chemical insights using weakly supported voltammetry: Ion pairing in the EC 2 reduction of 2,6-diphenylpyrylium in acetonitrile. ChemPhysChem, 13(1), 92–95.

MLA Style

Barnes, E., et al. “New Chemical Insights Using Weakly Supported Voltammetry: Ion Pairing in the EC 2 Reduction of 2,6-Diphenylpyrylium in Acetonitrile.” ChemPhysChem, vol. 13, no. 1, 2012, pp. 92–95.

Chicago Style

Barnes, E, Y Wang, SR Belding, and R Compton. 2012. “New Chemical Insights Using Weakly Supported Voltammetry: Ion Pairing in the EC 2 Reduction of 2,6-Diphenylpyrylium in Acetonitrile.” ChemPhysChem 13 (1): 92–95.
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Publisher copy:: 10.1002/cphc.201100569

Authors

+ Barnes, E More by this author

Role:: Author

+ Wang, Y More by this author

Role:: Author

+ Belding, SR More by this author

Role:: Author

+ Compton, R More by this author

Role:: Author

Journal:: ChemPhysChem More from this journal
Volume:: 13
Issue:: 1
Pages:: 92-95
Publication date:: 2012-01-16
DOI:: 10.1002/cphc.201100569
EISSN:: 1439-7641
ISSN:: 1439-4235

Language:: English
Keywords:: computational chemistry

reductions

reaction mechanisms

voltammetry

ion pairing
Pubs id:: pubs:342861
UUID:: uuid:7ac24b64-8f33-4ea0-be10-36ba1cca572a
Local pid:: pubs:342861
Source identifiers:: 342861
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2012

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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