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Gold Catalysis and Fluorine

Abstract:

Performing gold-catalyzed organic transformations in the presence of fluorinating reagents can lead to both fluorinated and non-fluorinated products. Gold(I) complexes can activate alkynes towards nucleophilic attack by fluoride leading to fluoroalkenes under mild conditions. Fluorinated products can also be prepared upon performing gold-catalyzed transformations in the presence of electrophilic sources of fluorine. In most cases, however, the combination of gold and electrophilic fluorinatin...

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Publication status:
Published

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Publisher copy:
10.1002/ijch.201000078

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
ISRAEL JOURNAL OF CHEMISTRY
Volume:
50
Issue:
5-6
Pages:
675-690
Publication date:
2010-12-05
DOI:
EISSN:
1869-5868
ISSN:
0021-2148
URN:
uuid:79395b76-d043-4779-90f9-e43cddbedc16
Source identifiers:
120294
Local pid:
pubs:120294

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