Journal article icon

Journal article

Dissolved Argon Changes the Rate of Diffusion in Room Temperature Ionic Liquids: Effect of the Presence and Absence of Argon and Nitrogen on the Voltammetry of Ferrocene

Abstract:

This work explores the effects of argon and nitrogen, two electrochemically and chemically inert gases frequently used in sample preparation of room temperature ionic liquid (RTIL) solutions, on the electrochemical characterization of ferrocene (Fc) dissolved in the RTIL 1-ethyl-3- methylimidazolium bis(trifluoromethanesulfonyl)imide ([C2mim] [NTf2]). Remarkably, chronoamperometrically determined diffusion coefficients of Fc in [C2mim][NTf2] are found to increase from 4.8 (±0.2) × 10-11 m2 s-...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/jp9015849

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
113
Issue:
18
Pages:
7750-7754
Publication date:
2009-05-07
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:7912719c-7f37-42d1-bdef-96d8a73216c8
Source identifiers:
41132
Local pid:
pubs:41132
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP