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ORGANOMETALLIC PHOTOELECTROCHEMISTRY - THE PHOTOOXIDATION OF AN (ARENE)CHROMIUM TRICARBONYL SYSTEM

Abstract:
The photoelectrochemical oxidation of the compound tricarbonyl(N,N, N′,N′-tetramethyl-1,4- phenylenediamine)chromium 1, has been studied using a platinum channel electrode. Maximum photocurrents are seen at an irradiation wavelength of 365 nm corresponding to a metal-to-ligand charge transfer absorption. By means of in situ electrochemical EPR and quantitative photocurrent/mass ' transport measurements the process is shown to be of the photo-CE type and a rate constant and approximate quantum yield are reported.
Publication status:
Published

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Publisher copy:
10.1039/p29930000039

Authors


COMPTON, R More by this author
BARGHOUT, R More by this author
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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Issue:
1
Pages:
39-42
Publication date:
1993-01-05
DOI:
EISSN:
1364-5471
ISSN:
0300-9580
URN:
uuid:78fa7486-cda4-478d-86f0-c00bf0a8d576
Source identifiers:
44058
Local pid:
pubs:44058
Language:
English

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