Journal article
ORGANOMETALLIC PHOTOELECTROCHEMISTRY - THE PHOTOOXIDATION OF AN (ARENE)CHROMIUM TRICARBONYL SYSTEM
- Abstract:
- The photoelectrochemical oxidation of the compound tricarbonyl(N,N, N′,N′-tetramethyl-1,4- phenylenediamine)chromium 1, has been studied using a platinum channel electrode. Maximum photocurrents are seen at an irradiation wavelength of 365 nm corresponding to a metal-to-ligand charge transfer absorption. By means of in situ electrochemical EPR and quantitative photocurrent/mass ' transport measurements the process is shown to be of the photo-CE type and a rate constant and approximate quantum yield are reported.
- Publication status:
- Published
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Authors
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 More from this journal
- Issue:
- 1
- Pages:
- 39-42
- Publication date:
- 1993-01-01
- DOI:
- EISSN:
-
1364-5471
- ISSN:
-
0300-9580
- Language:
-
English
- UUID:
-
uuid:78fa7486-cda4-478d-86f0-c00bf0a8d576
- Local pid:
-
pubs:44058
- Source identifiers:
-
44058
- Deposit date:
-
2012-12-19
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- Copyright date:
- 1993
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