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Two open-framework germanates with nickel complexes incorporated into the framework.

Abstract:

Two open-framework germanates, SUT-1 and SUT-2, have been synthesized under hydrothermal conditions using ethylenediamine (en, H(2)NCH(2)CH(2)NH(2)) as templates and Ni(NO(3))(2)·6H(2)O as the transition-metal source. Their frameworks are built with Ge(10) clusters and [Ni(en)(2)](2+) complexes. In both structures, Ge(10) clusters form square nets in the a-c plane, while the [Ni(en)(2)](2+) complexes bridge the square nets via Ni-O-Ge bonds to form 3D networks. They present the first examples...

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Publication status:
Published

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Publisher copy:
10.1021/ic2013478

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Journal:
Inorganic chemistry
Volume:
50
Issue:
20
Pages:
9921-9923
Publication date:
2011-10-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:77cbc392-6548-421f-b2fc-a98ffd90a49b
Source identifiers:
321974
Local pid:
pubs:321974
Language:
English

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