Journal article
Tetrahydrofuran amino acids: Secondary structure in tetrameric and octameric carbopeptoids derived from a D-allo 5-(aminomethyl)tetrahydrofuran-2-carboxylic acid
- Abstract:
- The synthesis of a D-allo-5-(azidomethyl)tetrahydrofuran-2-carboxylate as an amino acid precursor (in which the carboxylic acid is cis to the azidomethyl substituent and trans to the diol moiety) is reported from D-ribose. The oligomerisation of this monomer to dimeric, tetrameric and octameric carbopeptoids is described. NMR studies into the solution structures of cyclohexylidene-protected oligomers and of a deprotected tetramer with eight free hydroxy groups are described. © The Royal Society of Chemistry 2000.
- Publication status:
- Published
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Authors
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 More from this journal
- Issue:
- 21
- Pages:
- 3666-3679
- Publication date:
- 2000-01-01
- DOI:
- EISSN:
-
1364-5463
- ISSN:
-
1470-4358
- Language:
-
English
- Pubs id:
-
pubs:37588
- UUID:
-
uuid:77952a1c-852f-44c0-a076-a15329a9e07c
- Local pid:
-
pubs:37588
- Source identifiers:
-
37588
- Deposit date:
-
2012-12-19
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- Copyright date:
- 2000
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