Journal article

Structure, spectra, and intracluster chemistry of gas phase platinum nitrosyl ion-molecule complexes

Abstract:: The structures of gas-phase platinum – nitrosyl ion–molecule complexes, [Pt(NO)n] + (n =3-7), have been investigated using a combination of infrared photodissociation action spectroscopy and quantum chemical simulations. Nitric oxide binds in a combination of linear and bent motifs associated with nominal three- and one- electron donation, respectively, and there is clear evidence of a first solvation shell closing at six ligands. Oxygen rich complexes are also observed in the mass spectrum and their infrared spectra indicate formation of an N2O3 moiety. Calculations support the interpretation of [Pt(N2O3)(NO)n] + complexes arising from exothermic intracluster reactions in which [..(NO)3..]+ complexes form [..(NO2)(N2O)..]+ species from which the more weakly-bound nitrous oxide is lost.

Publication status:: Published

Peer review status:: Peer reviewed

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APA Style

Pearcy, P. A. J., Brewer, E. I., Meizyte, G., Harrington, S., Doll, M., Watson, P. D., Haakansson, C. T., & Mackenzie, S. R. (2025). Structure, spectra, and intracluster chemistry of gas phase platinum nitrosyl ion-molecule complexes. Physical Chemistry Chemical Physics, 27(45), 24256–24265.

MLA Style

Pearcy, PAJ, et al. “Structure, Spectra, and Intracluster Chemistry of Gas Phase Platinum Nitrosyl Ion-Molecule Complexes.” Physical Chemistry Chemical Physics, vol. 27, no. 45, 2025, pp. 24256–65.

Chicago Style

Pearcy, PAJ, EI Brewer, G Meizyte, et al. 2025. “Structure, Spectra, and Intracluster Chemistry of Gas Phase Platinum Nitrosyl Ion-Molecule Complexes.” Physical Chemistry Chemical Physics 27 (45): 24256–65.
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Files:: Pearcy_et_al_2025_Structure_spectra_and.pdf

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Pearcy_et_al_2025_Supplementary_material.pdf

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Publisher copy:: 10.1039/d5cp03460d

Authors

+ Pearcy, PAJ More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author
ORCID:: 0000-0003-2784-2892

+ Brewer, EI More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author

+ Meizyte, G More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author

+ Harrington, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author

+ Doll, M More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Chemistry Research Laboratory
Role:: Author
ORCID:: 0000-0002-4479-2025

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+ Engineering and Physical Sciences Research Council More from this funder

Funder identifier:: https://ror.org/0439y7842
Grant:: 639385 / B18R13173; EP/T021675/1

Publisher:: Royal Society of Chemistry
Journal:: Physical Chemistry Chemical Physics More from this journal
Volume:: 27
Issue:: 45
Pages:: 24256-24265
Publication date:: 2025-10-16
Acceptance date:: 2025-10-15
DOI:: 10.1039/d5cp03460d
EISSN:: 1463-9084
ISSN:: 1463-9076

Language:: English
Pubs id:: 2300045
Local pid:: pubs:2300045
Deposit date:: 2025-10-16
ARK identifier:: ark:/29072/ora_76fd0f117097423286d4e95b7dc0bad8

Terms of use

Copyright holder:: Pearcy et al
Copyright date:: 2025
Rights statement:: © 2025 The Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Licence:: CC Attribution (CC BY) 3.0

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