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Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides

Abstract:
Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c5cc00421g
Publication website:
http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/c5cc00421g

Authors

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Department:
University of Oxford
Role:
Author
More by this author
Department:
University of Oxford
Role:
Author


Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
51
Issue:
24
Pages:
5044-5047
Publication date:
2015-02-23
Acceptance date:
2015-02-13
DOI:
EISSN:
1364-548X
ISSN:
1359-7345


Language:
English
UUID:
uuid:764be43c-532f-4bde-a740-b9e6519ff4c3
Deposit date:
2015-09-15
ARK identifier:

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