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Journal article

Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate.

Abstract:
Samarium chloride and borohydride complexes of the diamide-diamine ligands (2-C5H4N)CH2N(CH2CH2NR)2(R = SiMe3 or mesityl) are described; the borohydride compounds are the first polydentate amide-supported single component lanthanide catalysts for the controlled polymerisation of polar monomers, and also represent the first lanthanide borohydride complex for the polymerisation of methyl methacrylate.
Publication status:
Published

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Publisher copy:
10.1039/b417279p

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
Dalton transactions (Cambridge, England : 2003) More from this journal
Issue:
3
Pages:
421-423
Publication date:
2005-02-01
DOI:
EISSN:
1477-9234
ISSN:
1477-9226


Language:
English
Pubs id:
pubs:51041
UUID:
uuid:7508b497-6909-4af8-8c66-a397cba48487
Local pid:
pubs:51041
Source identifiers:
51041
Deposit date:
2012-12-19

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