Journal article
A heterometallic σ-silane adduct from cooperative reactivity of an iron–aluminium complex
- Abstract:
- Protonation of a heterometallic silanide complex with an alcohol led to formation of a σ-silane complex. This reaction does not require a strong acid or a weakly coordinating anion. Both metals of the heterometallic complex play an important role, with the aluminium centre sequestering the anion generated in the protonation step.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Version of record, pdf, 1.3MB, Terms of use)
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- Publisher copy:
- 10.1039/d5cc06456b
Authors
- Publisher:
- Royal Society of Chemistry
- Journal:
- Chemical Communications More from this journal
- Publication date:
- 2025-12-05
- DOI:
- EISSN:
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1364-548X
- ISSN:
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1359-7345
- Language:
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English
- Pubs id:
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2348879
- UUID:
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uuid_74f07359-7832-44b4-ba46-e1b109631964
- Local pid:
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pubs:2348879
- Source identifiers:
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W4416845946
- Deposit date:
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2025-12-10
- ARK identifier:
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Terms of use
- Copyright date:
- 2025
- Licence:
- CC Attribution (CC BY)
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