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Synthesis, bonding and reactivity of a terminal titanium alkylidene hydrazido compound.

Abstract:

We report a detailed study of the reactions of the Ti=NNCPh2 alkylidene hydrazide functional group in [Cp*Ti{MeC(NiPr)2}(NNCPh2)] (8) with a variety of unsaturated and saturated substrates. Compound 8 was prepared from [Cp*Ti{MeC(NiPr)2}(NtBu)] and Ph2CNNH2. DFT calculations were used to determine the nature of the bonding for the Ti=NNCPh2 moiety in 8 and in the previously reported [Cp2Ti(NNCPh2)(PMe3)]. Reaction of 8 with CO2 gave dimeric [(Cp*Ti{MeC(NiPr)2}{μ-OC(NNCPh2)O})2] and the "doubl...

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Publication status:
Published

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Publisher copy:
10.1002/chem.201203905

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
19
Issue:
13
Pages:
4198-4216
Publication date:
2013-03-05
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:72ff6715-0f61-4e81-a1a0-df6c93e08618
Source identifiers:
384119
Local pid:
pubs:384119

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