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Isolation of the elusive [Ru(bipy)3]+: a key intermediate in photoredox catalysis

Abstract:
Photoredox catalysis has flourished in recent years, but due to its widespread utility applications have grown faster than mechanistic understanding. In this report we help to address this deficit by isolating and characterising one of the intermediates of the iconic photocatalyst [Ru(bipy)3]2+, and testing its initial photoreactivity towards common substrates.
Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1039/d3cc04375d

Authors

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Role:
Author
ORCID:
0000-0002-6547-9951
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
ORCID:
0000-0002-0851-655X
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Keble College
Role:
Author
ORCID:
0000-0003-1878-5857


More from this funder
Funder identifier:
https://ror.org/0439y7842
Grant:
EP/V056069/1
EP/S023828/1
EP/V056069/2


Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
59
Issue:
99
Pages:
14665-14668
Place of publication:
England
Publication date:
2023-11-15
Acceptance date:
2023-11-15
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pmid:
37991841


Language:
English
Pubs id:
1570264
Local pid:
pubs:1570264
Deposit date:
2025-03-28
ARK identifier:

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