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THE ENZYMATIC RING EXPANSION OF PENICILLINS TO CEPHALOSPORINS - SIDE-CHAIN SPECIFICITY

Abstract:
Structural variants of the acylamino side chain of penicillins have been tested as substrates for Deacetoxy/Deacetyl Cephalosporin C Synthetase from C.acremonium CO 728. A six carbon chain terminating in a carboxyl group was found to permit efficient ring expansion to cephems, with the exception of δ-(L-α-aminoadipoyl).1. © 1987.
Publication status:
Published

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Journal:
TETRAHEDRON
Volume:
43
Issue:
13
Pages:
3009-3014
Publication date:
1987-01-01
DOI:
ISSN:
0040-4020
Source identifiers:
185084
Language:
English
Pubs id:
pubs:185084
UUID:
uuid:6ed359ed-4fde-485a-8923-b7f8f158c8a0
Local pid:
pubs:185084
Deposit date:
2012-12-19

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