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Magnetic ground state of the one-dimensional ferromagnetic chain compounds M(NCS)(2)(thiourea)(2) (M = Ni, Co)

Abstract:

The magnetic properties of the two isostructural molecule-based magnets - Ni(NCS)2(thiourea)2, S=1 [thiourea=SC(NH2)2] and Co(NCS)2(thiourea)2, S=3/2 - are characterized using several techniques in order to rationalize their relationship with structural parameters and to ascertain magnetic changes caused by substitution of the spin. Zero-field heat capacity and muon-spin relaxation measurements reveal low-temperature long-range ordering in both compounds, in addition to Ising-like (D<0) si...

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Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1103/PhysRevMaterials.5.034401

Authors


Publisher:
American Physical Society Publisher's website
Journal:
Physical Review Materials Journal website
Volume:
5
Issue:
3
Article number:
34401
Publication date:
2021-03-03
Acceptance date:
2021-02-03
DOI:
EISSN:
2475-9953
ISSN:
2475-9953
Language:
English
Keywords:
Pubs id:
1171278
Local pid:
pubs:1171278
Deposit date:
2021-08-04

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