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Carbohydrate self‐assembly at surfaces: STM imaging of sucrose conformation and ordering on Cu(100)

Abstract:
Saccharides are ubiquitous biomolecules, but little is known about their interaction with, and assembly at, surfaces. By combining preparative mass spectrometry with scanning tunneling microscopy, we have been able to address the conformation and self-assembly of the disaccharide sucrose on a Cu(100) surface with subunit-level imaging. By employing a multistage modeling approach in combination with the experimental data, we can rationalize the conformation on the surface as well as the interactions between the sucrose molecules, thereby yielding models of the observed self-assembled patterns on the surface.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.201901340

Authors


More by this author
Role:
Author
ORCID:
0000-0002-5360-4719
More by this author
Role:
Author
ORCID:
0000-0002-4660-0306


Publisher:
Wiley
Journal:
Angewandte Chemie International Edition More from this journal
Volume:
58
Issue:
25
Pages:
8336-8340
Publication date:
2019-06-01
Acceptance date:
2019-04-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Pmid:
31018027


Language:
English
Keywords:
Pubs id:
995087
Local pid:
pubs:995087
Deposit date:
2021-02-25

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