Journal article
BaMnO3-x revisited: A structural and magnetic study
- Abstract:
-
The synthesis and structural characterization of 15R-, 8H-, 6H′-, and 10H-BaMnO3-x and 9R-Ba0.875-Sr0.125MnO 3 is described. Neutron powder diffraction data reveal a strong preference for the location of anion vacancies within the face-shared hexagonal layers of these phases. At high anion vacancy concentrations, Mn 2Og9-x dimer units become prevalent. Magnetic characterization indicates antiferro-magnetic order in all phases. Ordering temperatures are in the range 250 K < T < 270 K and...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/cm062055r
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Bibliographic Details
- Journal:
- CHEMISTRY OF MATERIALS
- Volume:
- 19
- Issue:
- 4
- Pages:
- 755-762
- Publication date:
- 2007-02-20
- DOI:
- EISSN:
-
1520-5002
- ISSN:
-
0897-4756
- Source identifiers:
-
40228
Item Description
- Language:
- English
- Pubs id:
-
pubs:40228
- UUID:
-
uuid:6b585b4d-e7ee-4ca8-8550-51846443802a
- Local pid:
- pubs:40228
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2007
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