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Methylzinc tetrahydroborate: investigation of the vapour phase by spectroscopic and quantum chemical techniques

Abstract:

Methylzinc tetrahydroborate vapour, as shown by its mass and infrared spectra, consists of an equilibrium mixture of monomeric and dimeric species; the proportion of the timer increases as the temperature is raised from 243 to 268 K (at pressures < 10-1 Torr). Consistent with the results of Density Functional Theory (DFT) calculations, the pattern of infrared bands of the matrix-isolated monomer points to a bidentate BH4 group and a tri-coordinate zinc centre. Close agreement between compu...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF MOLECULAR STRUCTURE
Volume:
444
Issue:
1-3
Pages:
29-46
Publication date:
1998-03-16
DOI:
ISSN:
0022-2860
URN:
uuid:6b30ecec-a31f-4265-a2a5-66437c4a1746
Source identifiers:
36528
Local pid:
pubs:36528

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