Journal article
Methylzinc tetrahydroborate: investigation of the vapour phase by spectroscopic and quantum chemical techniques
- Abstract:
-
Methylzinc tetrahydroborate vapour, as shown by its mass and infrared spectra, consists of an equilibrium mixture of monomeric and dimeric species; the proportion of the timer increases as the temperature is raised from 243 to 268 K (at pressures < 10-1 Torr). Consistent with the results of Density Functional Theory (DFT) calculations, the pattern of infrared bands of the matrix-isolated monomer points to a bidentate BH4 group and a tri-coordinate zinc centre. Close agreement between compu...
Expand abstract
- Publication status:
- Published
Actions
Access Document
- Publisher copy:
- 10.1016/S0022-2860(97)00314-1
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Bibliographic Details
- Journal:
- JOURNAL OF MOLECULAR STRUCTURE
- Volume:
- 444
- Issue:
- 1-3
- Pages:
- 29-46
- Publication date:
- 1998-03-16
- DOI:
- ISSN:
-
0022-2860
- Source identifiers:
-
36528
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:36528
- UUID:
-
uuid:6b30ecec-a31f-4265-a2a5-66437c4a1746
- Local pid:
- pubs:36528
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 1998
If you are the owner of this record, you can report an update to it here: Report update to this record