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Cascade palladium-catalyzed direct intramolecular arylation/alkene isomerization sequences: synthesis of indoles and benzofurans.

Abstract:
One route, two cycles: A palladium-catalyzed intramolecular direct arylation reaction combined with an isomerization step provided a straightforward synthetic route to both indoles and benzofurans (see scheme). Isolation and functionalization of intermediate alkene isomers allowed the formation of variants having substituents remote from the core. © 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/anie.201004097

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Journal:
Angewandte Chemie (International ed. in English)
Volume:
49
Issue:
43
Pages:
7958-7962
Publication date:
2010-10-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
73315
Language:
English
Keywords:
Pubs id:
pubs:73315
UUID:
uuid:6a7c3646-7d88-4b41-a258-8f297102c25f
Local pid:
pubs:73315
Deposit date:
2012-12-19

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