Journal article
New Sandwich and Half-Sandwich Titanium Hydrazido Compounds
- Abstract:
-
New mono- and bis-cyclopentadienyl terminal titanium hydrazido(2-) compounds were prepared by tert-butyl imide/N,N-disubstituted hydrazine exchange reactions. Reaction of Cp*Ti(NtBu)Cl(py) (1) with Ph 2NNH2 gave the terminal hydrazide Cp*Ti(NNPh 2)Cl(py) (4), whereas the corresponding reaction of CpTi(N tBu)Cl(py) gave the dimer Cp2Ti2(μ- η1:η1-NNPh2)(μ-η2: η1-NNPh2)Cl2. Reaction of 1 with Me 2NNH2 (1 equiv) also gave a dimer, Cp* 2Ti2(μ-η1:η1-NNMe 2)(μ-η2:η1-NNMe2)Cl 2 (8), while the reactio...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/om200068k
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Bibliographic Details
- Journal:
- ORGANOMETALLICS
- Volume:
- 30
- Issue:
- 8
- Pages:
- 2295-2307
- Publication date:
- 2011-04-25
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- Source identifiers:
-
135115
Item Description
- Language:
- English
- Pubs id:
-
pubs:135115
- UUID:
-
uuid:69fc41a0-fc62-4952-94be-0ee9e83193d6
- Local pid:
- pubs:135115
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2011
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