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New Sandwich and Half-Sandwich Titanium Hydrazido Compounds

Abstract:

New mono- and bis-cyclopentadienyl terminal titanium hydrazido(2-) compounds were prepared by tert-butyl imide/N,N-disubstituted hydrazine exchange reactions. Reaction of Cp*Ti(NtBu)Cl(py) (1) with Ph 2NNH2 gave the terminal hydrazide Cp*Ti(NNPh 2)Cl(py) (4), whereas the corresponding reaction of CpTi(N tBu)Cl(py) gave the dimer Cp2Ti2(μ- η1:η1-NNPh2)(μ-η2: η1-NNPh2)Cl2. Reaction of 1 with Me 2NNH2 (1 equiv) also gave a dimer, Cp* 2Ti2(μ-η1:η1-NNMe 2)(μ-η2:η1-NNMe2)Cl 2 (8), while the reactio...

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Publication status:
Published

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Publisher copy:
10.1021/om200068k

Authors


Schwarz, AD More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
ORGANOMETALLICS
Volume:
30
Issue:
8
Pages:
2295-2307
Publication date:
2011-04-25
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:69fc41a0-fc62-4952-94be-0ee9e83193d6
Source identifiers:
135115
Local pid:
pubs:135115
Language:
English

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