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Nanocarbon Paste Electrodes

Abstract:
The electrochemical behaviour of carbon paste electrodes prepared using nanocarbon and mineral oil was investigated and the results contrasted with different carbon and carbon pastes electrodes. The composition of carbon paste was studied by performing cyclic voltammetry performed in 0.1M KCl solution in the presence of 4.0mM Ru(NH3)6Cl3, a well-characterized redox system commonly used to test the electrode behaviour. After optimisation of the paste composition, the sensors chosen were tested for the analysis and characterization of three different systems: Ru(NH3)6 3+/2+, FcCH2OH/FcCH2OH+ and acetaminophen. The ability to obtain high quality voltammetry from the nanocarbon electrode was demonstrated and simulation of the voltammetry allowed the extraction of electrode kinetic parameters with high precision. © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/elan.201300364

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


More from this funder
Funding agency for:
Gan, P
Grant:
COY-15-EWI-RCFSA/N197-1
More from this funder
Funding agency for:
Lowinsohn, D
Grant:
Process 10080-12-0
More from this funder
Funding agency for:
Gan, P
Grant:
COY-15-EWI-RCFSA/N197-1


Journal:
ELECTROANALYSIS More from this journal
Volume:
25
Issue:
11
Pages:
2435-2444
Publication date:
2013-11-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397


Keywords:
UUID:
uuid:69d981a9-293a-45b6-8d1a-e828382c7455
Local pid:
pubs:440921
Source identifiers:
440921
Deposit date:
2014-02-10

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