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Endohedral metallofullerenes in self-assembled monolayers

Abstract:

A method has been developed for the attachment of a dithiolane group to endohedral metallofullerenes via a 1,3-dipolar cycloaddition reaction. This sulfur-containing functional group serves as an anchor, enabling efficient immobilisation of endohedral fullerenes on Au(111) surfaces at room temperature, directly from the solution phase. The functionalised fullerenes form disordered monolayers that exhibit no long-range ordering, which is attributed to both the strong bonding of the dithiolane ...

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Publisher copy:
10.1039/b915170b

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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
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Journal:
Physical Chemistry Chemical Physics
Volume:
12
Issue:
1
Pages:
123-131
Publication date:
2010-01-01
DOI:
ISSN:
1463-9076
Source identifiers:
178872
Language:
English
Pubs id:
pubs:178872
UUID:
uuid:69be81e9-b92c-41e4-9194-724d312e296f
Local pid:
pubs:178872
Deposit date:
2012-12-19

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