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Concise synthesis of highly substituted benzo[a]quinolizines by a multicomponent reaction/allylation/heck reaction sequence

Abstract:

The combination of the recently developed multicomponent construction of highly substituted 3,4-dihydropyridones with subsequent allylation and intramolecular Heck-type cyclization allows the straightforward construction of benzo[a]quinolizines, a class of polycyclic compounds that- despite their interesting pharmacological and photochemical properties- have little precedent in the literature. After optimization of the individual steps, we used this reliable three-step sequence to generate a ...

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Publisher copy:
10.1002/ejoc.201101170

Authors


Journal:
European Journal of Organic Chemistry More from this journal
Volume:
2012
Issue:
2
Pages:
275-280
Publication date:
2012-01-01
DOI:
EISSN:
1099-0690
ISSN:
1434-193X
Language:
English
Keywords:
Pubs id:
pubs:480336
UUID:
uuid:69481833-3088-473d-8b01-461d3ad831b0
Local pid:
pubs:480336
Source identifiers:
480336
Deposit date:
2014-08-22

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