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Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V^4+, x = 0; M = Ga^3+, x = 1): co-existence of ordered and disordered quantum spins in the V^4+ system.

Abstract:
The title compounds are bimetallic MOFs containing [Cu(pyz)2]^2+ square lattices linked by MF6^n- octahedra. In each, only the Cu^2+ spins exhibit long-range magnetic order below 3.5 K (M = V^4+) and 2.6 K (M = Ga^3+). The V^4+ spins remain disordered down to 0.5 K.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Files:
Publisher copy:
10.1039/c6cc05873f

Authors


Manson, JL More by this author
Schlueter, JA More by this author
Garrett, KE More by this author
Goddard, PA More by this author
Lancaster, T More by this author
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University of Chicago Argonne, LLC More from this funder
Engineering and Physical Sciences Research Council More from this funder
Hochfeld-Magnetlabor Dresden More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
52
Issue:
85
Pages:
12653-12656
Publication date:
2016-09-05
Acceptance date:
2016-09-27
DOI:
ISSN:
1364-548X and 1359-7345
Pubs id:
pubs:653511
URN:
uri:68f73bff-8f83-401f-955f-b7fc447f8adf
UUID:
uuid:68f73bff-8f83-401f-955f-b7fc447f8adf
Local pid:
pubs:653511
Language:
English
Keywords:

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