Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V^4+, x = 0; M = Ga^3+, x = 1): co-existence of ordered and disordered quantum spins in the V^4+ system.

Manson, JL; Schlueter, JA; Garrett, KE; Goddard, PA; Lancaster, T; Möller, JS; Blundell, S; Steele, AJ; Franke, I; Pratt, FL; Singleton, J; Bendix, J; Lapidus, SH; Uhlarz, M; Ayala-Valenzuela, O; McDonald, RD; Gurak, M; Baines, C

Abstract:

The title compounds are bimetallic MOFs containing [Cu(pyz)2]^2+ square lattices linked by MF6^n- octahedra. In each, only the Cu^2+ spins exhibit long-range magnetic order below 3.5 K (M = V^4+) and 2.6 K (M = Ga^3+). The V^4+ spins remain disordered down to 0.5 K.

Publication status:

Published

Peer review status:

Peer reviewed

Version:

Accepted manuscript

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

Your message (optional)
Please add any additional information to be included within the email.
Cite

Cite this record

APA Style

Manson, J. L., Schlueter, J. A., Garrett, K. E., Goddard, P. A., Lancaster, T., Möller, J. S., Blundell, S., Steele, A. J., Franke, I., Pratt, F. L., Singleton, J., Bendix, J., Lapidus, S. H., Uhlarz, M., Ayala-Valenzuela, O., McDonald, R. D., Gurak, M., & Baines, C. (2016). Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V^4+, x = 0; M = Ga^3+, x = 1): co-existence of ordered and disordered quantum spins in the V^4+ system. Chemical Communications, 52(85), 12653–12656.

MLA Style

Manson, J. L., et al. “Bimetallic MOFs (H3O)x[Cu(MF6)(Pyrazine)2]·(4 - x)H2O (M = V^4+, x = 0; M = Ga^3+, x = 1): Co-Existence of Ordered and Disordered Quantum Spins in the V^4+ System.” Chemical Communications, vol. 52, no. 85, Chemical Communications, 2016, pp. 12653–56.

Chicago Style

Manson, JL, JA Schlueter, KE Garrett, PA Goddard, T Lancaster, JS Möller, S Blundell, et al. 2016. “Bimetallic MOFs (H3O)x[Cu(MF6)(Pyrazine)2]·(4 - x)H2O (M = V^4+, x = 0; M = Ga^3+, x = 1): Co-Existence of Ordered and Disordered Quantum Spins in the V^4+ System.” Chemical Communications 52 (85): 12653–56.
Tweet
Print