Journal article
Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V^4+, x = 0; M = Ga^3+, x = 1): co-existence of ordered and disordered quantum spins in the V^4+ system.
- Abstract:
- The title compounds are bimetallic MOFs containing [Cu(pyz)2]^2+ square lattices linked by MF6^n- octahedra. In each, only the Cu^2+ spins exhibit long-range magnetic order below 3.5 K (M = V^4+) and 2.6 K (M = Ga^3+). The V^4+ spins remain disordered down to 0.5 K.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Accepted manuscript, pdf, 964.6KB)
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- Publisher copy:
- 10.1039/c6cc05873f
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Authors
Funding
University of Chicago Argonne, LLC
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Engineering and Physical Sciences Research Council
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Hochfeld-Magnetlabor Dresden
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Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Chemical Communications Journal website
- Volume:
- 52
- Issue:
- 85
- Pages:
- 12653-12656
- Publication date:
- 2016-09-01
- Acceptance date:
- 2016-09-27
- DOI:
- ISSN:
-
1364-548X and 1359-7345
- Source identifiers:
-
653511
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:653511
- UUID:
-
uuid:68f73bff-8f83-401f-955f-b7fc447f8adf
- Local pid:
- pubs:653511
- Deposit date:
- 2016-11-11
Terms of use
- Copyright holder:
- Royal Society of Chemistry
- Copyright date:
- 2016
- Notes:
- © The Royal Society of Chemistry 2016
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