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A Direct Three-Component Reaction for the Isolation of a Nonanuclear Iron(III) Phosphonate

Abstract:

The synthesis, structure, and magnetism of a nonanuclear iron(III) phosphonate, [Fe9III(μ3-O)4(O3PC5H9)3(O2CCMe3)13]·(EtOH)0.5·(Et2O)0.5 (1), is described. Compound 1 was obtained in the direct reaction of anhydrous ferric chloride, cyclopentylphosphonic acid, and pivalic acid in the presence of triethylamine. Compound 1 possesses a distorted icosahedral structure; nine of the vertices are occupied by FeIII, whereas three others are occupied by the phosphorus atoms of the cyclopentylphosphona...

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Publication status:
Published

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Publisher copy:
10.1002/ejic.201402371
Journal:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY More from this journal
Issue:
26
Pages:
4342-4348
Publication date:
2014-09-01
DOI:
EISSN:
1099-0682
ISSN:
1434-1948
Language:
English
Keywords:
Pubs id:
pubs:478419
UUID:
uuid:67fc13b5-e33c-4506-8bea-86c4982ce881
Local pid:
pubs:478419
Source identifiers:
478419
Deposit date:
2014-08-15

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