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Voltammetric demonstration of thermally induced natural convection in aqueous solution

Abstract:

In electrochemical systems imperfect thermostating inevitably leads to the presence of bulk convective flows. As recognised by Nernst [Z. Phys. Chem., 1904, 52] damping of these bulk convective flows next to a solid surface, or at the electrode, leads to diffusional mass transport predominating locally. This work questions the exclusivity of diffusional transport and provides hitherto unexplored physical insights into how thermally induced flows in bulk solution can, on both macro- and microe...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/C9CP01913H

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Oxford college:
Exeter College
Role:
Author
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Physical Chemistry Chemical Physics Journal website
Volume:
2019
Issue:
21
Article number:
9969
Publication date:
2019-04-25
Acceptance date:
2019-04-25
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
994604
Language:
English
Keywords:
Pubs id:
pubs:994604
UUID:
uuid:67d79c0f-0e02-4ca0-9f00-70b9c11b0412
Local pid:
pubs:994604
Deposit date:
2019-04-25

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