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Nickel and palladium complexes of Di-N-Heterocyclic carbenes

Abstract:

This thesis is concerned with the synthesis of two di-N-heterocyclic carbene ligands, and their reactivity towards nickel and palladium precursors in order to synthesise new organometallic pre-catalysts for a number of important reactions. The catalytic properties of a new rhodium C60 compound are also investigated, with relevance to the evaluation of C60 as a hydrogen storage medium.

Chapter 1 reviews the preparation and chemistry of N-heterocyclic carb...

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Peer review status:
Peer reviewed

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Department:
University of Oxford
Role:
Author
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
UUID:
uuid:679dade4-1d16-4918-b155-996250516783
Local pid:
polonsky:5:26
Source identifiers:
603838832
Deposit date:
2017-10-05

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