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Bonding in pentalene complexes and their recent applications

Abstract:
Molecular orbital (MO) theory is used to describe the bonding in transition metal pentalene complexes in a variety of its coordination modes. The various MO models account for structural parameters and lead to simple rules for electron counting in pentalene complexes. Recent applications of pentalene complexes are also reviewed, in the areas of small molecule activation and catalysis and as molecular models for conducting organometallic polymers.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.ccr.2016.12.006

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Oxford college:
Balliol College
Role:
Author
More from this funder
Funding agency for:
Kilpatrick, A
Grant:
RJP Williams Junior Research Fellowship
Publisher:
Elsevier Publisher's website
Journal:
Coordination Chemistry Reviews Journal website
Volume:
344
Pages:
238-262
Publication date:
2016-12-01
Acceptance date:
2016-12-19
DOI:
ISSN:
0010-8545
Source identifiers:
675329
Keywords:
Pubs id:
pubs:675329
UUID:
uuid:6775aad3-d9d1-4482-851f-8bb1f0a4b437
Local pid:
pubs:675329
Deposit date:
2017-02-08

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