Journal article
Synthesis, Characterization, and Polymerization Studies of Ethylenebis(hexamethylindenyl) Complexes of Zirconium and Hafnium
- Abstract:
-
The chemistry of a series of ansa-bridged ethylene-bis(hexamethylindenyl) zirconium and hafnium complexes has been explored. Treatment of EBI*Li2·THF0.38 with MCl4· THF2 (M = Zr, Hf) gives rac-EBI*MCl2 (rac-2, rac-3) and meso-EBI*MCl2 (meso-2, meso-3) (M = Zr and Hf), respectively. The rac-and meso-isomers can be separated by fractional crystallization. meso-EBI*ZrMe2 (meso-4) can be prepared by alkylation of meso-2 with MeLi·LiBr. The molecular structures of rac-and meso-2 and rac-and meso-3...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- ORGANOMETALLICS
- Volume:
- 30
- Issue:
- 4
- Pages:
- 800-814
- Publication date:
- 2011-02-28
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- Source identifiers:
-
124626
Item Description
- Language:
- English
- Pubs id:
-
pubs:124626
- UUID:
-
uuid:676999f9-ac91-42b1-85d6-ca186d47ddd6
- Local pid:
- pubs:124626
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2011
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