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Thesis

Hydrogen bonding phase-transfer catalysis with sodium azide and potassium cyanide

Abstract:

Hydrogen Bonding-Phase Transfer Catalysis (HB-PTC) enables use of alkali metal fluoride salts as reactive reagents in enantioselective catalysis and this platform has been successfully applied towards enantioselective fluorination. This thesis details a study into the structure and reactivity of hydrogen bonded azide and cyanide anions and the development of enantioselective reactions using sodium azide and potassium cyanide under HB-PTC for the synthesis of enantioenriched organoazide and...

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Division:
MPLS
Department:
Chemistry
Role:
Author

Contributors

Role:
Supervisor
ORCID:
0000-0001-8638-5308
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Name:
Engineering and Physical Sciences Research Council
Grant:
EP/L015838/1
Programme:
EPSRC Centre for Doctoral Training in Synthesis for Biology and Medicine
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Keywords:
Subjects:
Deposit date:
2022-01-15

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