Journal article
Mitigated phase transition during first cycle of a Li-rich layered cathode studied by in operando synchrotron X-ray powder diffraction
- Abstract:
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In operando synchrotron X-ray powder diffraction (SXPD) studies were conducted to investigate the phase transition of Li-rich Li(Li0.2Ni0.13Mn0.54Co0.13)O2 and Cr-doped Li(Li0.2Ni0.13Mn0.54Co0.03Cr0.10)O2 cathodes during the first charge/discharge cycle. Crystallographic (lattice parameters) and mechanical (domain size and microstrain) information was collected from SXPD full pattern refinement. It was found that Cr substitution at Co-site benefits in suppressing the activation of Li2MnO3 dom...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Accepted manuscript, pdf, 1.2MB)
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- Publisher copy:
- 10.1039/c5cp04801j
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Authors
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Physical Chemistry Chemical Physics: PCCP Journal website
- Volume:
- 18
- Issue:
- 6
- Pages:
- 4745-4752
- Publication date:
- 2016-01-15
- Acceptance date:
- 2016-01-15
- DOI:
- ISSN:
-
1463-9084 and 1463-9076
- Pmid:
-
26799191
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:597837
- UUID:
-
uuid:6736fcfa-18a8-49fa-92cd-0ba039c3a352
- Local pid:
- pubs:597837
- Deposit date:
- 2016-09-02
Terms of use
- Copyright holder:
- The Owner Societies
- Copyright date:
- 2016
- Notes:
-
This is an
accepted manuscript of a journal article published by the Royal Society of Chemistry in Physical Chemistry Chemical Physics on 2016-01-15, available online: http://dx.doi.org/10.1039/c5cp04801j
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