Journal article
Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides
- Abstract:
- Aryl substituted 2,2,2-trifluorodiazoethanes undergo rhodium(II)-catalysed insertion reactions with tin hydrides affording the corresponding α-(trifluoromethyl)benzyl stannanes. This reactivity contrasts with that of diazo esters which predominantly afford CH2 reduction products in the presence of tin hydrides. The first example of asymmetric insertion into tin hydrides using diazo compounds is also described. In addition, this system extends to asymmetric germanium hydride and silane insertion.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Preview, Accepted manuscript, pdf, 1.3MB, Terms of use)
-
- Publisher copy:
- 10.1016/j.tet.2018.11.022
Authors
- Publisher:
- Elsevier
- Journal:
- Tetrahedron More from this journal
- Volume:
- 75
- Issue:
- 1
- Pages:
- 17-25
- Publication date:
- 2018-11-23
- Acceptance date:
- 2018-11-10
- DOI:
- EISSN:
-
1464-5416
- ISSN:
-
0040-4020
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:951023
- UUID:
-
uuid:6651cb0f-de92-4b1d-b0a7-2227a4f9e4cf
- Local pid:
-
pubs:951023
- Source identifiers:
-
951023
- Deposit date:
-
2019-03-05
- ARK identifier:
Terms of use
- Copyright holder:
- Elsevier Ltd.
- Copyright date:
- 2018
- Rights statement:
- © 2018 Elsevier Ltd. All rights reserved.
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from Elsevier at: https://doi.org/10.1016/j.tet.2018.11.022
If you are the owner of this record, you can report an update to it here: Report update to this record