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Anion-templated calix[4]arene-based pseudorotaxanes and catenanes.

Abstract:

We present the rational design and anion-binding properties of the first anion-templated pseudorotaxanes and catenanes in which the "wheel" component is provided by a calix[4]arene macrobicyclic unit. The designs and syntheses of two new calix[4]arene macrobicycles, 2 and 3, are presented, and the abilities of these new species both to bind anions and to undergo anion-dependent pseudorotaxane formation are demonstrated. Furthermore, it is shown that performing ring-closing metathesis reaction...

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Publication status:
Published

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Publisher copy:
10.1002/chem.200700041

Authors


Lankshear, MD More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
13
Issue:
14
Pages:
3861-3870
Publication date:
2007
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:65f68387-9fb2-41bf-8671-0a896fc1136f
Source identifiers:
33808
Local pid:
pubs:33808

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