Journal article

Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes.

Abstract:: Water-soluble, high-molecular-weight polycobaltocenium polyelectrolytes have been prepared by ring-opening polymerization (ROP) techniques. Anionic polymerization of a strained 19-electron dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium chloride resulted in the formation of oligomers with up to nine repeat units. Thermal ROP of dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium nitrate resulted in the formation of high-molecular-weight polycobaltocenium nitrate, a redox-active cobalt-containing polyelectrolyte.

Publication status:: Published

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APA Style

Mayer, U., Gilroy, J., O'Hare, D., & Manners, I. (2009). Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes. Journal of the American Chemical Society, 131(30), 10382–10383.

MLA Style

Mayer, U., et al. “Ring-Opening Polymerization of 19-Electron [2]Cobaltocenophanes: a Route to High-Molecular-Weight, Water-Soluble Polycobaltocenium Polyelectrolytes.” Journal of the American Chemical Society, vol. 131, no. 30, 2009, pp. 10382–83.

Chicago Style

Mayer, U, J Gilroy, D O'Hare, and I Manners. 2009. “Ring-Opening Polymerization of 19-Electron [2]Cobaltocenophanes: a Route to High-Molecular-Weight, Water-Soluble Polycobaltocenium Polyelectrolytes.” Journal of the American Chemical Society 131 (30): 10382–83.
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Publisher copy:: 10.1021/ja903513e

Authors

+ Mayer, U More by this author

Role:: Author

+ Gilroy, J More by this author

Role:: Author

+ O'Hare, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Manners, I More by this author

Role:: Author

Journal:: Journal of the American Chemical Society More from this journal
Volume:: 131
Issue:: 30
Pages:: 10382-10383
Publication date:: 2009-08-01
DOI:: 10.1021/ja903513e
EISSN:: 1520-5126
ISSN:: 0002-7863

Language:: English
Pubs id:: pubs:51251
UUID:: uuid:65b83f6c-37df-4580-9c1c-628b6b47fba7
Local pid:: pubs:51251
Source identifiers:: 51251
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2009

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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