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Electrochemo-mechanical properties of red phosphorus anodes in lithium, sodium, and potassium ion batteries

Abstract:
The measurement of mechanical properties of red phosphorus (RP) and diffusivity of Li, Na, and K in RP allowed the development of a model that simulates the evolution of stresses within an RP particle during alkali-ion charging. We show that RP particles can be charged at high current densities without catastrophic failure of the particle. The model was validated by in situ TEM charging with extreme conditions of anisotropic ion diffusion and high current density.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.matt.2020.09.017

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
ORCID:
0000-0003-0114-8405
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
ORCID:
0000-0003-3462-2943


Publisher:
Cell Press
Journal:
Matter More from this journal
Volume:
3
Issue:
6
Pages:
2012-2028
Publication date:
2020-12-02
Acceptance date:
2020-09-16
DOI:
EISSN:
2590-2385
ISSN:
2590-2393


Language:
English
Keywords:
Pubs id:
1145275
Local pid:
pubs:1145275
Deposit date:
2021-01-12

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