Journal article
A nonpeptidic reverse turn that promotes parallel sheet structure stabilized by C-H...O hydrogen bonds in a cyclopropane gamma-peptide.
- Abstract:
- (Chemical Equation Presented) A twist of fate: Parallel-turn linkers comprising an amino acid derived alcohol conjoined with an aromatic amide through a flexible linkage adopt reverseturn conformations. Cyclopropane tetra-and hexapeptide analogues form a C-H⋯O hydrogen-bond-stabilized parallel-sheet conformation (see scheme). NMR studies confirm the presence of hydrogen bonds in these structures. © 2008 Wiley-VCH Verlag GmbH and Co. KGaA.
- Publication status:
- Published
Actions
Authors
- Journal:
- Angewandte Chemie (International ed. in English) More from this journal
- Volume:
- 47
- Issue:
- 37
- Pages:
- 7099-7102
- Publication date:
- 2008-01-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:58753
- UUID:
-
uuid:63070314-3108-4ee3-898e-749e7b75e3cf
- Local pid:
-
pubs:58753
- Source identifiers:
-
58753
- Deposit date:
-
2012-12-19
Terms of use
- Copyright date:
- 2008
If you are the owner of this record, you can report an update to it here: Report update to this record