Journal article icon

Journal article

Methylzinc tetrahydroborate: Physical and chemical properties and crystal structure at low temperature

Abstract:

Methylzinc tetrahydroborate, MeZnBH4, has been prepared by two routes and initially characterized by elemental analysis and its spectroscopic properties. The structure has been determined by X-ray crystallography at 150 K [trigonal, space group R3c, a = b = 15.831(10), c = 8.36(2) Å, Z = 18, R = 0.072] to reveal helical polymers in which MeZn+ and BH4- units alternate, with the latter functioning as a bidentate ligand with respect to both of the adjacent metal atoms. It thus resembles the str...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/dt9960000853

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Parsons, S More by this author
Pulham, CR More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
6
Pages:
853-859
Publication date:
1996-03-21
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:62dab271-ef32-499d-b415-383fcc4b41b2
Source identifiers:
45189
Local pid:
pubs:45189
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP