- Abstract:
-
Methylzinc tetrahydroborate, MeZnBH4, has been prepared by two routes and initially characterized by elemental analysis and its spectroscopic properties. The structure has been determined by X-ray crystallography at 150 K [trigonal, space group R3c, a = b = 15.831(10), c = 8.36(2) Å, Z = 18, R = 0.072] to reveal helical polymers in which MeZn+ and BH4- units alternate, with the latter functioning as a bidentate ligand with respect to both of the adjacent metal atoms. It thus resembles the str...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/dt9960000853
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
- Issue:
- 6
- Pages:
- 853-859
- Publication date:
- 1996-03-21
- DOI:
- EISSN:
-
1364-5447
- ISSN:
-
0300-9246
- URN:
-
uuid:62dab271-ef32-499d-b415-383fcc4b41b2
- Source identifiers:
-
45189
- Local pid:
- pubs:45189
- Language:
- English
- Copyright date:
- 1996
Journal article
Methylzinc tetrahydroborate: Physical and chemical properties and crystal structure at low temperature
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