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Methylzinc tetrahydroborate: Physical and chemical properties and crystal structure at low temperature

Abstract:

Methylzinc tetrahydroborate, MeZnBH4, has been prepared by two routes and initially characterized by elemental analysis and its spectroscopic properties. The structure has been determined by X-ray crystallography at 150 K [trigonal, space group R3c, a = b = 15.831(10), c = 8.36(2) Å, Z = 18, R = 0.072] to reveal helical polymers in which MeZn+ and BH4- units alternate, with the latter functioning as a bidentate ligand with respect to both of the adjacent metal atoms. It thus resembles the str...

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Publication status:
Published

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Publisher copy:
10.1039/dt9960000853

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
6
Pages:
853-859
Publication date:
1996-03-21
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
Source identifiers:
45189
Language:
English
Pubs id:
pubs:45189
UUID:
uuid:62dab271-ef32-499d-b415-383fcc4b41b2
Local pid:
pubs:45189
Deposit date:
2012-12-19

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