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PERIPHERAL CHEMICAL-REACTIONS

Abstract:
Forward scattering of the products of direct exoergic atom transfer reactions is proposed as an indication for a peripheral attraction: a reaction in which an atom at the periphery of the reactants is abstracted. Model computations for the O(1D) + N2O reaction are used to illustrate the proposed mechanism. The opacity function has a peak at higher impact parameters which is correlated with the forward scattering. Potential energy surfaces which do not manifest peripheral attraction lead to backwards scattering of the products. © 1993.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
CHEMICAL PHYSICS LETTERS More from this journal
Volume:
210
Issue:
4-6
Pages:
423-431
Publication date:
1993-07-30
DOI:
ISSN:
0009-2614
Language:
English
Pubs id:
pubs:52573
UUID:
uuid:620284d7-80d2-4ad3-aea1-fed9bad85da8
Local pid:
pubs:52573
Source identifiers:
52573
Deposit date:
2012-12-19

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