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ROTATING-DISK ELECTRODES - ECE AND DISP1 PROCESSES

Abstract:

Theory is presented for the shape of current-voltage curves measured at a rotating-disc electrode for the cases where the substrate reacts via either an ECE or a DISP1 process in which the kinetic step is sufficiently fast to allow the use of the reaction-layer concept in the theoretical treatment. When the electrode potential for the electrode reaction can be found under conditions where there are no complications of coupled kinetics, analysis of the shift in half-wave potential with disc ro...

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Publication status:
Published

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Publisher copy:
10.1039/f19878301261

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I
Volume:
83
Issue:
4
Pages:
1261-1268
Publication date:
1987-01-01
DOI:
ISSN:
0300-9599
Source identifiers:
42749
Language:
English
UUID:
uuid:61f3a0cd-68b1-46e5-81fe-048c6ea3dd62
Local pid:
pubs:42749
Deposit date:
2012-12-19

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