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Electrosynthetic reduction of 1-iodoadamantane forming 1,1'-biadamantane and adamantane in aprotic solvents: insonation switches the mechanism from dimerisation to exclusive monomer formation.

Abstract:

The combination of ultrasound and electrochemistry -sonoelectrochemistry can produce a variety of effects within an electrochemical system including enhanced mass transport, in situ cleaning of an electrode surface, diminution of the diffusion layer, and possible induction of new reactions by sonochemical enhancement of follow-up reactions post-electron transfer. Herein, we show that ultrasound provides a useful extra dimension to electrosynthesis via a switch in the sonoelectroorganic mechan...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Ultrasonics sonochemistry More from this journal
Volume:
14
Issue:
5
Pages:
502-508
Publication date:
2007-07-01
DOI:
EISSN:
1873-2828
ISSN:
1350-4177
Language:
English
Keywords:
UUID:
uuid:617a90d1-55b4-4cdf-b08c-9dd9d41d4c2f
Local pid:
pubs:33725
Source identifiers:
33725
Deposit date:
2012-12-19

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