Hidden truchet architecture in zinc p-hydroxybenzoate

Journal article

We redetermine the structure of the disordered metal–organic framework Zn(hba) (hba2− = the dianion of 4-hydroxybenzoic acid). Using singlecrystal X-ray diffraction measurements, we characterise the structured diffuse scattering that is experimentally observed for this material and which is characteristic of strongly correlated disorder. We use geometric and crystal chemical arguments to propose a general model for correlated disorder in Zn(hba), and then relate this model to a specific realisation of so-called Truchet tilings. Using Monte Carlo simulations, we proceed to show that the model so developed is simultaneously consistent with both the average crystal structure solution described previously, and the structured diffuse scattering reported here. The existence of ordered analogues with different, but related, chemistry suggests scope for control over correlated disorder in this family of metal–organic frameworks. Our study illustrates the potential for a Truchet-tile formalism to help describe and understand more generally the correlated disorder that can occur.

Authors: Greenbaum, G; Dolling, T; Kholina, Y; Windsor, H; Goodwin, A

• Publication status: Accepted
• Peer review status: Peer reviewed
• Publisher: American Chemical Society
• Journal: Journal of the American Chemical Society
• Acceptance date: 2026-10-07
• EISSN: 1520-5126
• ISSN: 0002-7863
• Language: English