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Strategies towards the synthesis of calyciphylline A-type Daphniphyllum alkaloids.

Abstract:
The Daphniphyllum alkaloids are a diverse family of natural products rich in number and structural diversity that have been known for many decades. However, the structurally unique subclass of calyciphylline A-type alkaloids has only recently been discovered and is relatively unexplored. Several noteworthy core syntheses and the development of a wide range of novel synthetic strategies have been achieved. This includes strategies based on intramolecular Michael addition, Pd-catalysis, cycloaddition, and Mannich-type reactions. This review will provide an overview of these synthetic studies.
Publication status:
Published

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Publisher copy:
10.1039/c3np70115h

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Publisher:
Royal Society of Chemistry
Journal:
Natural product reports More from this journal
Volume:
31
Issue:
4
Pages:
550-562
Publication date:
2014-04-01
DOI:
EISSN:
1460-4752
ISSN:
0265-0568


Language:
English
Keywords:
Pubs id:
pubs:451007
UUID:
uuid:60a85064-de3b-411e-aa41-35219b2beec6
Local pid:
pubs:451007
Source identifiers:
451007
Deposit date:
2014-05-18

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