- Abstract:
-
Conventional intercalation cathodes for lithium batteries store charge in redox reactions associated with the transition metal cations, e.g. Mn3+/4+ in LiMn2O4, and this limits the energy storage of Li-ion batteries. Compounds such as Li[Li0.2Ni0.2Mn0.6]O2 exhibit a capacity to store charge in excess of the transition metal redox reactions. The additional capacity occurs at and above 4.5 V vs. Li+/Li. The capacity at 4.5 V is dominated by oxidation of the O2- anions accounting for ~0.43 e-/fo...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 2.9MB)
-
- Publisher copy:
- 10.1021/jacs.6b05111
-
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- Funding agency for:
- Bruce, P
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 138
- Issue:
- 35
- Pages:
- 11211–11218
- Publication date:
- 2016-08-08
- DOI:
- EISSN:
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1520-5126
- ISSN:
-
0002-7863
- Pubs id:
-
pubs:638076
- URN:
-
uri:606673be-f8d4-4127-9f1e-22dea5b3dd36
- UUID:
-
606673be-f8d4-4127-9f1e-22dea5b3dd36
- Local pid:
- pubs:638076
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
- Copyright © 2016 American Chemical Society. This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Journal article
Anion redox chemistry in the cobalt free 3D transition metal oxide intercalation electrode Li[Li0.2Ni0.2Mn0.6]O2
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+ Engineering and Physical Sciences Research Council
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